This section contains the engineering properties of the “Multiphase” alloys. These alloys, based on the quaternary of cobalt, nickel, chromium, and molybdenum, can be work-strengthened and aged to ultrahigh strengths with good ductility and corrosion resistance.
MP35N is a vacuum induction, vacuum arc remelted alloy which can be work-strengthened and aged to ultrahigh strengths. This alloy is suitable for parts requiring ultrahigh strength, good ductility and excellent corrosion and oxidation resistance up to 700°F.
Manufacturing Considerations — The work hardening characteristics of MP35N are similar to 304 stainless steel. Drawing, swaging, rolling, and shear forming are excellent deforming methods for work strengthening the alloy. The machinability of MP35N is similar to the nickel-base alloys.
Environmental Considerations — MP35N has excellent corrosion, crevice corrosion and stress corrosion resistance in seawater. Due to the passivity of MP35N, a galvanically active coating, such as aluminum or cadmium, may be required to prevent galvanic corrosion of aluminum joints. Initial tests have indicated that MP35N does not appear to be susceptible to hydrogen embrittlement.
Short time exposure to temperatures above 700°F causes a decrease in ductility (elongation and reduction of area) at temperature. Mechanical properties at room temperature are not affected significantly by unstressed exposure to temperatures up to 50 degrees below the aging temperature (1000 to 2000°F) for up to 100 hours.
Note: Shown as printed in the handbook. The aging temperature “1000 to 2000°F” may be a typo: the Heat Treatment paragraph below gives 1000 to 1200°F.
Heat Treatment — After work strengthening, MP35N is aged at 1000 to 1200°F for 4 to 4½ hours and air cooled.
Material specifications for MP35N are presented in Table 7.4.1.0(a). The room-temperature mechanical and physical properties for MP35N are presented in Tables 7.4.1.0(b) and (c). The effect of temperature on physical properties is shown in Figure 7.4.1.0.
| Specification | Form |
|---|---|
| AMS 5844 | Bar (solution treated, and cold drawn) |
| AMS 5845 | Bar (solution treated, cold drawn and aged) |
| Specification | AMS 5845 | |||
|---|---|---|---|---|
| Form | Bar | |||
| Condition | Solution treated, cold drawn, and aged | |||
| Diameter, in.a | ≤0.800 | 0.801-1.000 | 1.001-1.750 | |
| Basis | A | B | S | S |
| Mechanical Properties: | ||||
| Ftu, ksi: | ||||
| L | 260b | 275 | 260 | 260 |
| LT | ··· | ··· | ··· | ··· |
| Fty, ksi: | ||||
| L | 230c | 266 | 230 | 230 |
| LT | ··· | ··· | ··· | ··· |
| Fcy, ksi: | ||||
| L | ··· | ··· | ··· | ··· |
| LT | ··· | ··· | ··· | ··· |
| Fsu, ksi | 145 | 147 | 145 | ··· |
| Fbru, ksi: | ||||
| (e/D = 1.5) | ··· | ··· | ··· | ··· |
| (e/D = 2.0) | ··· | ··· | ··· | ··· |
| Fbry, ksi: | ||||
| (e/D = 1.5) | ··· | ··· | ··· | ··· |
| (e/D = 2.0) | ··· | ··· | ··· | ··· |
| e, percent (S basis): | ||||
| L | 8 | ··· | 8 | 8 |
| RA, percent (S basis): | ||||
| L | 35 | ··· | 35 | 35 |
| E, 103 ksi | 34.0 | |||
| Ec, 103 ksi | ··· | |||
| G, 103 ksi | 11.7 | |||
| μ | ··· | |||
| Physical Properties: | ||||
| ω, lb/in.3 | 0.304 | |||
| C, Btu/(lb)(°F) | 0.18 (32 to 70&°;F) | |||
| K and α | See Figure 7.4.1.0 | |||
| a Tensile specimens are located at T/2 location for bars 0.800 inch and under in diameter or distance between parallel sides and at T/4 location of larger size bars. The strength of bar, especially large diameter, may vary significantly from center to surface; consequently, caution should be exercised in machining parts from bars over 0.800 inch in diameter since strengths may be lower than design values depending on depth of material removed from surface. | ||||
| b The T99 value of 266 ksi is higher than specification minimum. | ||||
| c The T99 value of 256 ksi is higher than specification minimum. | ||||
| Specification | AMS 5844 | |
|---|---|---|
| Form | Bar | |
| Condition | Solution treated and cold drawn | |
| Diameter, in.a | ≤1.000 | 1.001-1.750 |
| Basis | S | S |
| Mechanical Properties: | ||
| Ftu, ksi: | ||
| L | 260 | 260 |
| LT | ··· | ··· |
| Fty, ksi: | ||
| L | 230 | 230 |
| LT | ··· | ··· |
| Fcy, ksi: | ||
| L | ··· | ··· |
| LT | ··· | ··· |
| Fsu, ksi | 145 | ··· |
| Fbru, ksi: | ||
| (e/D = 1.5) | ··· | ··· |
| (e/D = 2.0) | ··· | ··· |
| Fbry, ksi: | ||
| (e/D = 1.5) | ··· | ··· |
| (e/D = 2.0) | ··· | ··· |
| e, percent: | ||
| L | 8 | 8 |
| RA, percent: | ||
| L | 35 | 35 |
| E, 103 ksi | 34.0 | |
| Ec, 103 ksi | ··· | |
| G, 103 ksi | 11.7 | |
| μ | ··· | |
| Physical Properties: | ||
| ω, lb/in.3 | 0.304 | |
| C, Btu/(lb)(°F) | 0.18 (32 to 70&°;F) | |
| K and α | See Figure 7.4.1.0 | |
| a Tensile specimens are located at T/2 location for bars 0.800 inch and under in diameter or distance between parallel sides and at T/4 location for larger size bars. The strength of bar, especially large diameter may vary significantly from center to surface; consequently, caution should be exercised in machining parts from bars over 0.800 inch in diameter since strengths may be lower than design values depending on depth of material removed from surface. | ||
The handbook plots these properties on one graph with a separate y-axis for each. Here each one has its own chart, over the same temperature range.
Thermal expansion coefficient (α)
How much the metal grows, per inch, for each °F. Mean value from 70 °F to the temperature shown. Units: 10⁻⁶ in/in/°F. Metric: × 1.8 = 10⁻⁶/K
Thermal conductivity (K)
How fast heat flows through the metal, at the temperature shown. Units: Btu/(hr·ft·°F). Metric: × 1.731 = W/(m·K)
Figure 7.4.1.0. Effect of temperature on the physical properties of MP35N alloy.
Elevated temperature curves for various mechanical properties are shown in Figures 7.4.1.1.1, 7.4.1.1.4 (a) and (b), and 7.4.1.1.5. Typical tensile stress-strain curves at room and elevated temperatures are shown in Figure 7.4.1.1.6.
Figure 7.4.1.1.1. Effect of temperature on the tensile ultimate strength (Ftu) and the tensile yield strength (Fty) of cold worked and aged MP35N bar, Ftu = 260 ksi. Strength at temperature, exposure up to 1/2 hr.
Figure 7.4.1.1.4(a). Effect of temperature on the dynamic tensile modulus (E) of MP35N alloy bar. Dynamic modulus at temperature, exposure up to 1/2 hr. Typical. Note: The reduction in dynamic modulus due to elevated temperature may be significantly less than the reduction in static modulus.
Figure 7.4.1.1.4(b). Effect of temperature on the dynamic shear modulus (G) of MP35N alloy bar. Dynamic modulus at temperature, exposure up to 1/2 hr. Typical. Note: The reduction in dynamic modulus due to elevated temperature may be significantly less than the reduction in static modulus.
Figure 7.4.1.1.5. Effect of temperature on the elongation (e) of cold worked and aged MP35N bar, Ftu = 260 ksi. Elongation at temperature, exposure up to 1/2 hr. Typical.
Figure 7.4.1.1.6. Typical tensile stress-strain curves at room and elevated temperatures for cold worked and aged MP35N bar, Ftu = 260 ksi. 1/2-hr exposure, longitudinal. Ramberg-Osgood n (RT) = 13, n (400°F) = 14, n (700°F) = 15. Typical.
MP159 is a vacuum induction, vacuum arc remelted alloy, based on cobalt, nickel, chromium, iron, and molybdenum, which can be work-strengthened and aged to ultrahigh strength. This alloy is suitable for parts requiring ultrahigh strength, good ductility, and excellent corrosion and oxidation resistance up to 1100°F. The alloy maintains its ultrahigh strength very well at temperatures up to 1100°F.
Manufacturing Considerations — The work hardening characteristics of MP159 are similar to MP35N and 304 stainless steel. Drawing, swaging, rolling, and shear forming are excellent deforming methods for work strengthening the alloy. The machinability of MP159 is similar to MP35N and the nickel-base alloys.
Environmental Considerations — MP159 has excellent corrosion, crevice corrosion, and stress corrosion resistance in various hostile environments. Due to the passivity of MP159, a galvanically active coating, such as aluminum or cadmium, may be required to prevent galvanic corrosion of aluminum joints. Initial tests have indicated that MP159 does not appear to be susceptible to hydrogen embrittlement.
Heat Treatment — After work strengthening, MP159 is aged at 1200 to 1250°F ± 25°F for 4 to 4½ hours and air cooled.
Material specifications for MP159 are presented in Table 7.4.2.0(a). The room temperature mechanical and physical properties for MP159 are presented in Tables 7.4.2.0(b) and (c). The effect of temperature on thermal expansion is shown in Figure 7.4.2.0.
| Specification | Form |
|---|---|
| AMS 5842 | Bar (solution treated and cold drawn) |
| AMS 5843 | Bar (solution treated, cold drawn, and aged) |
| Specification | AMS 5843 | ||||
|---|---|---|---|---|---|
| Form | Bar | ||||
| Condition | Solution treated, cold drawn, and aged | ||||
| Diameter, in.a | ≤0.500 | 0.501-0.800 | 0.801-1.750 | ||
| Basis | A | B | A | B | S |
| Mechanical Properties: | |||||
| Ftu, ksi: | |||||
| L | 260b | 269 | 260b | 269 | 260 |
| LT | ··· | ··· | ··· | ··· | ··· |
| Fty, ksi: | |||||
| L | 250c | 262 | 250c | 262 | 250 |
| LT | ··· | ··· | ··· | ··· | ··· |
| Fcy, ksi: | |||||
| L | ··· | ··· | ··· | ··· | ··· |
| LT | ··· | ··· | ··· | ··· | ··· |
| Fsu, ksi | 131 | 144 | ··· | ··· | ··· |
| Fbru, ksi: | |||||
| (e/D = 1.5) | ··· | ··· | ··· | ··· | ··· |
| (e/D = 2.0) | ··· | ··· | ··· | ··· | ··· |
| Fbry, ksi: | |||||
| (e/D = 1.5) | ··· | ··· | ··· | ··· | ··· |
| (e/D = 2.0) | ··· | ··· | ··· | ··· | ··· |
| e, percent (S basis): | |||||
| L | 6 | ··· | 6 | ··· | 6 |
| RA, percent (S basis): | |||||
| L | 32 | ··· | 32 | ··· | 32 |
| E, 103 ksi | 35.3 | ||||
| Ec, 103 ksi | ··· | ||||
| G, 103 ksi | 11.3 | ||||
| μ | 0.37 (solution treated condition) | ||||
| Physical Properties: | |||||
| ω, lb/in.3 | 0.302 | ||||
| C and K | ··· | ||||
| α, 10−6 in./in./°F | See Figure 7.4.2.0 | ||||
| a Tensile specimens are located at T/2 location for bars 0.800 inch and under in diameter or distance between parallel sides and at T/4 location for larger size bars. The strength of bar, especially large diameter, may vary machining parts from bars over 0.800-inch in diameter since strengths may be lower than design values depending on depth of material removed from surface. | |||||
| b S-Basis. The rounded T99 value of 265 ksi is higher than specification minimum. | |||||
| c S-Basis. The rounded T99 value of 253 ksi is higher than specification minimum. | |||||
| Specification | AMS 5842 | |
|---|---|---|
| Form | Bar | |
| Condition | Solution treated, cold drawn, and aged | |
| Diameter, in.a | ≤0.500 | 0.501-1.750 |
| Basis | S | S |
| Mechanical Properties: | ||
| Ftu, ksi: | ||
| L | 260 | 260 |
| LT | ··· | ··· |
| Fty, ksi: | ||
| L | 250 | 250 |
| LT | ··· | ··· |
| Fcy, ksi: | ||
| L | ··· | ··· |
| LT | ··· | ··· |
| Fsu, ksi | 131 | ··· |
| Fbru, ksi: | ||
| (e/D = 1.5) | ··· | ··· |
| (e/D = 2.0) | ··· | ··· |
| Fbry, ksi: | ||
| (e/D = 1.5) | ··· | ··· |
| (e/D = 2.0) | ··· | ··· |
| e, percent: | ||
| L | 6 | 6 |
| RA, percent: | ||
| L | 32 | 32 |
| E, 103 ksi | 35.3 | |
| Ec, 103 ksi | ··· | |
| G, 103 ksi | 11.3 | |
| μ | 0.37 (solution treated condition) | |
| Physical Properties: | ||
| ω, lb/in.3 | 0.302 | |
| C and K | ··· | |
| α, 10−6 in./in./°F | See Figure 7.4.2.0 | |
| a Tensile specimens are located at T/2 location for bars 0.800 inch and under in diameter or distance between parallel sides and at T/4 location for larger size bars. The strength of bar, especially large diameter may vary significantly from center to surface; consequently, caution should be exercised in machining parts from bars over 0.800 inch in diameter since strengths may be lower than design values depending on depth of material removed from surface. | ||
Thermal expansion coefficient (α)
How much the metal grows, per inch, for each °F. Mean value from 77 °F to the temperature shown. Units: 10⁻⁶ in/in/°F. Metric: × 1.8 = 10⁻⁶/K
Figure 7.4.2.0. Effect of temperature on thermal expansion (a) of MP159 alloy bar.
The effect of temperature on tension modulus of elasticity and shear modulus is presented in Figure 7.4.2.1.4. A typical stress-strain curve at room temperature is shown in Figure 7.4.2.1.6.
Figure 7.4.2.1.4. Effect of temperature on the tensile modulus (E) and shear modulus (G) of MP159 alloy bar. Dynamic modulus at temperature, exposure up to 1/2 hr. Typical. Note: The reduction in dynamic modulus due to elevated temperature may be significantly less than the reduction in static modulus.
Figure 7.4.2.1.6. Typical tensile stress-strain curve at room temperature for cold worked and aged MP159 alloy bar. Thickness: 0.530 in. Longitudinal. Ramberg-Osgood n (RT) = 13. Typical.